Compressive behavior of MWCNT/epoxy composite mats

Mats of vertically-aligned multiwall carbon nanotubes were grown in an thermal CVD reactor with simultaneous feed of the catalyst and carbon precursors. Mats were soaked into epoxy resin solutions without any prior chemical modification and then cured to produce composite plates of z-axis nano-reinforcement. Direct observations of the epoxy–CNT interactions at the nanoscale revealed that epoxy interacted naturally with the MWCNTs without affecting their physical characteristics, alignment, or the mat’s morphology. The compressive behavior of the pristine and composite mats was consistent with mechanical predictions accounting for an elastic regime followed by elastic instability and compaction. Strong evidence of reinforcement in the MWCNT/epoxy composites was indicated by increased strength, stiffness and toughness values with respect to the as-grown mats and pure polymer. The elastic instability strain of the composites was of the order of 0.4.     

Comparison of the Frying Performance of Olive Oil and Palm Superolein

Abstract: Deep‐fat frying is an important method of food preparation in which foods are immersed in hot oil. Repeated use of frying oils is a common practice, and in the presence of atmospheric oxygen it produces various undesirable reactions in used oils. Stable frying oils usually require low linolenic acid (LnA < 3%), increased oleic acid (OA > 40%), and decreased linoleic acid (LA < 50%). The aim of this study was to establish the behavior of palm superolein (PSO) (OA 45%; LA 12.5%; LnA 0.2%) and olive oil (OO) during repeated, discontinuous deep frying of French fries. The behavior of the oils under controlled heating conditions was also studied by maintaining all of the process variables the same as those in deep frying, except that there was no food in the oil. The PSO selected to be tested in this study may represent an alternative to OO as a frying medium. Although PSO presented a faster increase in some oxidation indices, such as free fatty acid and total polar compounds, for other indicators, PSO showed better behavior than OO (less formation of C8:0 and lower peroxide value). Practical Application: The super palm olein selected for use in this study can be suggested as a suitable replacement for olive oil for frying and cooking purposes because it provides higher oxidative stability besides the beneficial effects of olive oil on human health. In fact, several studies have indicated that palm oil exhibits similar frying performance to high‐oleic oils, with the advantages of greater availability in the market and a lower price.     

Serological cross-reactions between Coxiella burnetii and Legionella micdadei

PURPOSE: The bronchodilator effect of salbutamol formulated in hydrofluoroalkane-134a (HFA-134a), a chlorofluorocarbon (CFC)-free propellant for metered dose inhalation (MDI) devices, was compared with that of salbutamol formulated in CFC in anesthetized dogs. METHODS: Bronchospasms were induced by the intravenous injection of histamine, and bronchial resistance was measured by the method of Konzett and Rossler. RESULTS: While the placebo vehicles (HFA-134a and CFC propellants) had no significant effect on histamine-induced bronchospasms, the salbutamol/HFA-134a and salbutamol/CFC MDI formulations had equivalent dose-related inhibitory effects. CONCLUSIONS: These data indicated that salbutamol formulated in HFA-134a and that in CFC propellant are bioequivalent.     

Translocation of particles and inflammatory responses after exposure to fine particles and nanoparticles in an epithelial airway model

Background  

Experimental studies provide evidence that inhaled nanoparticles may translocate over the airspace epithelium and cause increased cellular inflammation. Little is known, however, about the dependence of particle size or material on translocation characteristics, inflammatory response and intracellular localization.     

The Interconnections of the LHC Cryomagnets at CERN: Strategy Applied and First Results of the Industrialization Process

The final interconnections of the LHC superconducting magnets in the underground tunnel are performed by a contractor on a result-oriented basis. A consortium of firms was awarded the contract after competitive tendering based on a technical and commercial specification. The implementation of the specific technologies and tooling developed and qualified by CERN has required an important effort to transfer the know-how and implement the follow-up of the contractor. This paper summarizes the start-up phase and the difficulties encountered. The organization and management tools put in place during the ramping-up phase are presented. In addition to contractual adaptations of the workforce, several configuration changes to the workflows were necessary to reach production rates compatible with the overall schedule and with the different constraints: availability of magnets, co-activities with magnets transport and alignment, handling of non-conformities, etc. Also the QA procedures underwent many changes to reach the high level of quality mandatory to ensure the LHC performance. The specificities of this worksite are underlined and first figures of merit of the learning process are presented.     

Improving macroscopic physical and mechanical properties of thick layers of aligned multiwall carbon nanotubes by annealing treatment

In this work we present a systematic study of the effects of high temperature treatments on the macroscopic physical and mechanical properties of millimeters thick layers of self-standing vertically aligned multi wall carbon nanotubes (MWCNTs).Annealing treatments were carried out on pristine MWCNT chunks in argon gas, in the temperature range of 1500–2200 °C. The analysis showed a change in most of the physical properties as an effect of the graphitization process.Raman results showed a monotonic increase in the crystallite size as the annealing temperature increases due to the lattice defect removal kinetic. Improvement in thermal stability exhibited by thermo-gravimetric analysis in oxidative environment witness a significant reduction in defectiveness.X-ray diffraction confirmed a higher degree of ordering after the annealing process and indicated no significant re-arrangement of the interlayer spacing between the graphene shells. Loading tests showed, beside a negligible change of maximum load, an increase in elastic modulus proportional to the annealing temperature.     

Charge Separation in BaTiO3 Nanocrystals: Spontaneous Polarization Versus Point Defect Chemistry

The fate of photogenerated charges within ferroelectric metal oxides is key for photocatalytic applications. The authors study the contributions of i) tetragonal distortion, responsible for spontaneous polarization, and ii) point defects, on charge separation and recombination within BaTiO₃ (BTO) nanocrystals of cubic and tetragonal structure. Electron paramagnetic resonance (EPR) in combination with O₂ photoadsorption experiments show that BTO nanocrystals annealed at 600 °C have a charge separation yield enhanced by a factor > 10 compared to TiO₂ anatase nanocrystals of similar geometries. This demonstrates for the first time the beneficial effect of the BTO perovskite nanocrystal lattice on charge separation. Strikingly, charge separation is considerably hindered within BTO nanoparticles annealed ≥ 600 °C, due to the formation of Ba–O divacancies that act as charge recombination centers. The opposing interplay between tetragonal distortion and annealing-induced defect formation inside the lattice highlights the importance of defect engineering within perovskite nanoparticles.